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In the realm of two-dimensional material frameworks, single-element graphene-like lattices, known as Xenes, pose several issues concerning their environmental stability, with implications for their use in technology transfer to a device layout. In this Discussion, we scrutinize the chemical reactivity of epitaxial silicene, taken as a case in point, in oxygen-rich environments. The oxidation of silicene is detailed by means of a photoemission spectroscopy study upon carefully dosing molecular oxygen under vacuum and subsequent exposure to ambient conditions, showing different chemical reactivity. We therefore propose a sequential Al2O3 encapsulation of silicene as a solution to face degradation, proving its effectiveness by virtue of the interaction between silicene and a silver substrate. Based on this method, we generalize our encapsulation scheme to a large number of metal-supported Xenes by taking into …
The Royal Society of Chemistry
Publication date: 
30 Dec 2019

Alessandro Molle, Gabriele Faraone, Alessio Lamperti, Daniele Chiappe, Eugenio Cinquanta, Christian Martella, Emiliano Bonera, Emilio Scalise, Carlo Grazianetti

Biblio References: 
Faraday Discussions